Staining and Tanning Developers
Bergger’s instructions for PMK change four things that have nothing to do with development. The stop bath must not be acid. The fixer must be non-tanning. The wash runs 20 to 30 minutes rather than the usual five to ten, because “the image colouring intensifies during washing”. And a hypo eliminator — a product whose entire purpose is to shorten a wash — must not be used, because it “would weaken the colouring of the negative”.
A developer that reaches three baths downstream of itself is telling you that it left something behind in the film. It did: a pyro negative carries two densities in the same layer, one made of silver and one made of the developer’s own oxidation product, and every instruction above exists to protect the second one.
What the course can say about the product, and what it cannot
Section titled “What the course can say about the product, and what it cannot”This page begins with its gap rather than ending with it, because everything else is built on top of the gap and a reader should know that from the start.
Established, from sources this course has read. The oxidation product of pyrogallol is coloured. It is deposited in the film alongside the silver, in proportion to the amount of development. It hardens the gelatin where development happened. Sulfite suppresses it, in a dose-dependent way.
Not established, and not asserted anywhere on this page. What the coloured product is. What its formula is. What reaction forms it. And by what mechanism it cross-links gelatin. The pyrogallol encyclopaedia entry says the same in the same words, and this lesson does not quietly supply what that page says the course could not find.
Sulfite is the dial, and a staining developer is that dial turned down
Section titled “Sulfite is the dial, and a staining developer is that dial turned down”Kodak’s primer teaches the preservative through pyro, because pyro shows it best, and it does so as a graded experiment rather than an assertion: no sulfite gives a very yellow negative whose image consists partly of silver and partly of oxidised pyrogallol; sulfite present gives a much less yellow one, because the sulfite is oxidised instead of the agent; a great deal of sulfite gives almost as blue an image as Elon, whose oxidation product is not deposited in a coloured form.
The lesson on the alternative agents drew that series. What follows from it is the design constraint that shapes every formula on this page:
A staining developer cannot carry a normal preservative, because the preservative’s job is to destroy exactly the substance the stain is made of. There is no formulation that gets both. A pyro developer is therefore a badly preserved developer on purpose, and every practical difficulty with these formulae — the two-part storage, the short working life, the sensitivity to how much air the solution meets — descends from that single fact.
Proportional stain, general stain, and how to tell them apart
Section titled “Proportional stain, general stain, and how to tell them apart”The stain a formulator wants is the one that tracks the silver. Bergger describes it precisely: “a yellow-green tint surrounds each silver grain and fills the usually empty space between them and becomes an intrinsic part of the image”, so that “the density of a pyro negative is therefore the conjunction of two densities, that of the silver and that of the coloration”.
Where the stain sits, and what tanning does to the gelatin around it
- Proportional stain — coloured product deposited in proportion to the development, filling the space between the grains
- Tanned gelatin — the same product hardening the layer where development happened; it swells less when wet
- General stain — colour in areas that did not develop; not image, and behaves as base density
General stain is the same colour in the wrong place: an overall tint that reaches the clear areas of the negative, which never developed and therefore have no image density to be proportional to. It comes from oxidation product formed in the solution rather than at a grain, and from oxidation product that has not been washed out, which is why the wash matters. Diagnostically the two are easy to tell apart on a light box — proportional stain leaves the film base and the rebate clear; general stain colours them too.
Stain as density: which colour you measure it in decides what it is worth
Section titled “Stain as density: which colour you measure it in decides what it is worth”A densitometer gives a different answer for a stained negative depending on what light it uses, and this is not an artefact. A yellow-green deposit absorbs blue strongly and green weakly and red hardly at all, so:
- Read in visual or green light, the stain contributes modestly and the negative looks close to what the silver alone would give.
- Read in blue or ultraviolet light — which is what a printing paper mostly sees — the stain contributes heavily, and the negative behaves as though it had far more contrast than a visual reading suggests.
Why a stained negative has two characteristic curves
- Blue or UV density: silver plus stain
- Visual or green density: silver alone
Show the numbers behind this plot
| Series | Relative log exposure | Density |
|---|---|---|
| Blue or UV density: silver plus stain | -2.00 | 0.10 |
| Blue or UV density: silver plus stain | -1.60 | 0.12 |
| Blue or UV density: silver plus stain | -1.30 | 0.20 |
| Blue or UV density: silver plus stain | -1.00 | 0.38 |
| Blue or UV density: silver plus stain | -0.60 | 0.72 |
| Blue or UV density: silver plus stain | -0.20 | 1.08 |
| Blue or UV density: silver plus stain | 0.20 | 1.38 |
| Blue or UV density: silver plus stain | 0.60 | 1.60 |
| Blue or UV density: silver plus stain | 1.20 | 1.76 |
| Visual or green density: silver alone | -2.00 | 0.10 |
| Visual or green density: silver alone | -1.60 | 0.11 |
| Visual or green density: silver alone | -1.30 | 0.17 |
| Visual or green density: silver alone | -1.00 | 0.30 |
| Visual or green density: silver alone | -0.60 | 0.52 |
| Visual or green density: silver alone | -0.20 | 0.72 |
| Visual or green density: silver alone | 0.20 | 0.90 |
| Visual or green density: silver alone | 0.60 | 1.02 |
| Visual or green density: silver alone | 1.20 | 1.10 |
On variable-contrast paper: an inference, labelled as one
Section titled “On variable-contrast paper: an inference, labelled as one”ILFORD’s technical information on MULTIGRADE papers explains how they work, and the mechanism is entirely about the blue-to-green ratio of the printing light. Exposure to blue light activates all the emulsions and gives a high-contrast image; exposure to green light activates only part of them and gives a low-contrast one. Hence the filters: “a magenta filter absorbs green light and transmits blue” for hard, “a yellow filter absorbs blue and transmits green” for soft.
Now put a yellow-green negative in front of that paper. The stain is itself a yellow filter, and it is densest in the highlights.
For alternative processes, which print by ultraviolet, the same logic points the other way and the evidence is weaker still. Bostick and Sullivan’s Pyrocat-HD sheet reports that “other users have reported reduced printing times with UV light sources compared with PMK negatives (for alt process work) due to the different stain color”. That is a manufacturer relaying user reports — a tier-3 claim inside a tier-1 document — and the course records it as such rather than as evidence that one stain colour prints faster than another.
Tanning, and the four things it changes
Section titled “Tanning, and the four things it changes”Eder’s history dates the discovery to the end of the 1870s: Leon Warnerke found the tanning action of pyrogallol on silver bromide plates and reported in 1881 that only the unexposed parts of such a film remained soluble in warm water, the exposed and tanned parts being insoluble. Eder had already pointed out that the relief left by alkaline pyrogallol without sulfite could be made high enough to mould from and used as a printing plate. For two generations, the tanning was the reason to use pyro at all.
For a photographer today it changes four things.
- The layer swells less where it developed. A hardened region takes up less water, which changes how everything after the developer penetrates it.
- The fixer must not harden as well. Bergger is unambiguous: “a non-tanning bath is essential for good subsequent coloration of the negative”, and recommends an acid-free fixer. A hardening fixer on top of a tanned layer locks the stain’s precursors in or drives them out, depending on whom you ask; what is documented is only that the maker forbids it.
- The wash lengthens rather than shortens. Twenty to thirty minutes, because the colouring intensifies during it — which means washing is part of image formation here and not merely the removal of residues.
- Edge behaviour. Bostick and Sullivan call Pyrocat-HD “a semi-compensating, high-definition developer”, and Bergger says PMK gives “negatives with very sharp outlines and very detailed highlights”. Both are manufacturers describing their own product; neither offers a mechanism, and the course does not supply one. What it can say is that these are low-sulfite, high-dilution, single-agent baths, which is the recipe for adjacency effects whether or not the tanning contributes anything of its own.
One claim you will meet and will not find here. Pyro is often said to make a negative more permanent, on the argument that the stain shields the silver from oxidation. No document in this course’s corpus makes that claim or supplies evidence for it — not Bergger’s datasheet, not Bostick and Sullivan’s, not Kodak’s primer, and not the conservation literature the course reads for permanence questions. The tanning is documented, the stain is documented, and the leap from either to image permanence is not. Treat it as an open question, and notice that it would be testable: two identically exposed negatives, one stained and one not, accelerated and read against each other.
The four formulae, and what provenance each of them has
Section titled “The four formulae, and what provenance each of them has”Rule 6 gives four different answers to the same question here, and the differences are the lesson.
| Formula | What the course holds | What it prints |
|---|---|---|
| Kodak D-1, standard A.B.C. pyro | Kodak’s own 1928 primer, with all three stock solutions and both working dilutions | The whole formula |
| PMK | Bergger’s 2020 datasheet: dilution, capacity, temperature, processing, hazards — and no ingredient list | Behaviour, dilution and handling only |
| Pyrocat-HD | Bostick and Sullivan’s kit sheet: behaviour, agitation schemes, comparative claims — and no named agents at all | Behaviour only |
| 510-Pyro | A development-time chart whose data is credited to a community database, with no composition | Nothing at all |
Kodak D-1 is published and is printed. Stock A carries 60 g of pyrogallol per litre with 9.8 g of sodium bisulfite and 1.1 g of potassium bromide; stock B carries 105 g of sodium sulfite per litre; stock C carries 75 g of sodium carbonate per litre. For tray work, one part of each with seven of water, which makes a working solution of 6 g of pyro, 10.5 g of sulfite and 7.5 g of carbonate per litre, 7 to 9 minutes at 18 °C. The tank version uses eleven parts of water instead of seven and runs 13 to 15 minutes.
Read the working numbers against D-76 and the whole design is visible at once: 10.5 grams of sulfite per litre against D-76’s hundred, a tenth as much. That is not a small preservative; it is a deliberately inadequate one, and it is the difference between a developer that hides its oxidation product and one that prints it.
PMK is a manufacturer’s product with an unusually informative datasheet and no formula on it. Bergger states that it is “a pyrogallol-based developer… adapted to modern films by Gordon Hutchings in the 1980s”, supplied as solution A of 250 mL and solution B of 500 mL, used at 1+2+100 to make 25 litres of working solution, with a capacity of 1,000 cm² of film per litre, an hour of working life in an open vessel, and a stated shelf life of up to ten years for both concentrates even half-filled. None of that is a composition, and this course prints none.
Pyrocat-HD goes further in the same direction: the kit sheet describes what the developer does at length and does not name a single ingredient, so it is evidence about behaviour and claims and about nothing else. King’s cited advantages over PMK — about a third of a stop more effective speed, 10 to 15 per cent shorter times, more consistent staining, lower toxicity, no streaking or mottling with reduced agitation — are claims by the formulator, reported by his supplier, and the course labels them that way.
510-Pyro is where the discipline is most visible. The document in the corpus is a development-time chart. It carries no ingredients, no quantities and no mixing instruction, and its header credits the times to a community database rather than to the supplier’s own measurement. There is therefore nothing to print, and the question of triethanolamine as a solvent — which the curriculum asked the course to verify, along with its hazards — does not arise, because the course cannot establish that it is in the product. A formula the course cannot source is not a formula the course discusses the safety of.
Two-part storage, and the logic that produces it
Section titled “Two-part storage, and the logic that produces it”A staining developer has to solve a problem it created. It cannot carry enough preservative to keep, because the preservative is what kills the stain. So it keeps the agent and the alkali apart until the moment of use, and preserves the agent bottle with an acid sulfite instead of a neutral one.
Kodak Limited’s 1949 handbook states the general rule for the whole class: developers “which are particularly susceptible to aerial oxidation often are divided into two or three solutions in which the developing agent is kept separate from the alkali, thus reducing oxidation”. The 1928 primer gives the chemistry underneath: a developing agent stored for a long time keeps best with an acid sulfite such as sodium bisulfite rather than sodium sulfite, which is slightly alkaline, and bisulfite “keeps satisfactorily in more dilute solutions and is a better preservative than sulfite in the absence of carbonate”. It names pyro among the readily oxidisable agents customarily kept that way.
Kodak’s own D-1 does exactly this: pyro with bisulfite and bromide in A, the sulfite alone in B, the carbonate alone in C, and the keeping-properties table lists D-1 as stored in three solutions. PMK and Pyrocat-HD are the same idea in modern packaging — an A and a B that meet in the tank.
The corollary matters more than the rule. The stability of a two-part developer belongs to the parts, not to the mixture. Bergger’s ten-year claim is for the concentrates; the working solution is given one hour in an open vessel. Nothing about a long-lived concentrate implies a long-lived bath, and treating the two as the same number is the commonest way to spoil a session with these developers.
Toxicology: two agents, two different levels, and no procedure on this page
Section titled “Toxicology: two agents, two different levels, and no procedure on this page”The pyrogallol and catechol entries carry the hazard data and the reasoning behind each classification; this section states the outcome and what follows for practice.
Pyrogallol is Level B — the advanced home laboratory. Its aggregated GHS classification is Warning with the irritant and health-hazard pictograms, and three statements are unanimous across every reporting notifier: harmful in contact with skin, harmful if inhaled, and suspected of causing genetic defects. There is no NIOSH Pocket Guide entry and no EH40 workplace exposure limit, and HSE’s own introduction to that list warns that absence from it does not indicate that a substance is safe. Bergger’s own datasheet is blunter than any of that: pyrogallol is “toxic to health, causing kidney, liver, circulatory disorders, or even death”, is toxic by inhalation, skin contact and ingestion, is a phenol and can cause burns, and brief skin contact leaves a dark stain while prolonged contact can cause a burn resembling a heat burn.
Catechol is Level C — engineered extraction, controlled waste and supervision, which a home does not have. Its classification is Danger, with an acute-toxicity pictogram that pyrogallol does not carry, a minority but substantial notification of “may cause cancer”, and a NIOSH skin notation meaning that absorption through intact skin contributes materially to exposure. The course’s position is that a reader may study catechol chemistry and may not weigh catechol powder at home.
- A pyro negative is two densities in one layer: silver, and a coloured oxidation product deposited in proportion to development. Everything unusual about processing one exists to protect the second.
- The course cannot name the coloured product, give an equation for it, or describe the cross-linking mechanism, and does not. Three sourced facts — it is coloured, it deposits with the silver, it hardens the gelatin — are what the whole page is built on.
- Sulfite is the dial. Kodak’s graded experiment runs from a very yellow negative at zero sulfite to an almost blue one at high sulfite. A staining developer is a deliberately under-preserved developer, and every practical difficulty follows from that.
- Proportional stain is image; general stain is fog with a colour. The rebate tells you which you have.
- The stain reads differently in blue and in green light, which is why a stained negative has two contrast values. Its behaviour on variable-contrast paper is the course’s inference from two Tier-1 statements, not a claim either source makes.
- Four formulae, four provenance verdicts. Kodak D-1 is printed in full; PMK and Pyrocat-HD are taught as behaviour because their sheets carry no composition; 510-Pyro is taught as nothing, because the only document held is a time chart with community-sourced data.
- Two-part storage is forced by the chemistry, and the concentrates’ shelf life says nothing about the working solution’s — ten years against one hour, on the same sheet.
- Pyrogallol is Level B and catechol is Level C, and this lesson gives no procedure for either.
Check your understanding
Sources for this page
12 cited · checked 2026-09-04
- 01Elementary Photographic ChemistryEastman Kodak Company, 1928§ Chapter III: the commonest developing agents and the ranking by reduction potential; the preservative and the graded pyrogallol experiment — no sulfite giving a very yellow negative whose image is partly silver and partly oxidised pyrogallol, sulfite giving a much less yellow one and a great deal of sulfite giving almost as blue an image as Elon; the statement that pyro oxidises far more readily than Elon or para-aminophenol; Formula D-1, the standard A.B.C. pyro, in three stock solutions with its tray and tank dilutions and times; Chapter VII: the keeping of pyro, two-solution and three-solution storage, sodium bisulphite as the better preservative for readily oxidisable agents, and scum on standing developersarchive.org/details/elementaryphotog00east_0tier 1, primary2026-09-04
- 02Chemicals and Formulae, 3rd edition (one of a series of Kodak photographic handbooks)Kodak Limited, 1949§ Making up solutions, including the instruction that sodium bisulphite is added with the sulphite; Storage of developer solutions, including the division of readily oxidised developers into two or three solutions to keep the developing agent away from the alkali; the keeping-properties table showing formula D-1 stored in three solutionsarchive.org/details/KodakChemicalsAndFormulaetier 1, primary2026-09-04
- 03BERGGER PMK DatasheetBERGGER, 2020§ PMK properties — the yellow-green tint surrounding each silver grain and filling the space between them, the density of a pyro negative as the conjunction of two densities, and the claims of increased sensitivity, more pronounced definition and reduced grain; Preparation — two solutions A and B and the standard dilution of 1 part A, 2 parts B and 100 parts water; Conservation — a shelf life of up to ten years even in half-filled bottles; Use — capacity of 1000 square centimetres per litre, one hour of working-solution life in open vessels, and a temperature range of 21 to 27 degrees C with emulsion deterioration above 27 to 28; Film processing — the essential 3 to 5 minute pre-wet, agitation every 15 seconds, a non-acid stop bath, an essential non-tanning fixing bath, a 20 to 30 minute wash because the colouring intensifies during washing, and the instruction not to use a hypo eliminator; Development errors; Toxicity; the Time and Temperature chart with its meter settingsbergger.com/fr/index.phptier 1, primary2026-09-04
- 04Pyrocat-HD Film Developer: kit instructionsBostick & Sullivan, Inc.§ Introduction — Pyrocat-HD as a semi-compensating, high-definition developer formulated by Sandy King as an alternative to PMK, and the advantages King cites; the report attributed to other users of reduced printing times with UV light sources for alt-process work because of the different stain colour, and of reduced base-plus-fog density; the development recommendations; the note that doubling the B solution takes FP4 Plus to a contrast index of 0.52 in 5 minutes 30 instead of 8 minutesbostick-sullivan.com/wp-content/uploads/2022/03/Pyro-HD-instructions.pdftier 1, primary2026-09-04
- 05510-Pyro Development ChartBostick & Sullivan, Inc.§ The whole document — a development-time chart headed 'Data Courtesy of digitaltruth.com', carrying no composition, no ingredient list and no mixing instructionbostick-sullivan.com/wp-content/uploads/2022/03/510-Pyro-Development-Chart.pdftier 1, primary2026-09-04
- 06History of PhotographyJosef Maria Eder, translated by Edward Epstean, 1945§ Braconnot and the reduction of silver nitrate by pyrogallic acid, 1831; development with pyrogallic acid by Regnault and Liebig, 1851; the pyro-ammonia developer for gelatine silver bromide plates and the yellowish or brownish stain it left; Berkeley's addition of sodium sulphite in 1882 and Mawson and Swan's potassium metabisulphite in 1886; Warnerke and the tanning action of pyrogallol, and the utilization of tanned gelatine silver bromide filmsarchive.org/details/EderHistoryPhotographytier 1, primary2026-09-04
- 07Photographic Facts and FormulasE. J. Wall, F.C.S., F.R.P.S., 1924§ Developers — pyrogallol and pyro-ammonia, and Wall's note that pyro-ammonia is rarely used on account of its variability; Stand development — the Wratten & Wainwright pyro-soda formula in two solutions, Bothamley's pyrocatechin in two solutions, and the pyro-soda formulae of Claudy, Harris and Munkmanarchive.org/details/photographicfact00walltier 1, primary2026-09-04
- 08Contrast Control for ILFORD MULTIGRADE Variable Contrast Papers, technical informationHARMAN technology Limited (ILFORD Photo), 2010§ How MULTIGRADE papers work — the emulsions and their differing sensitivity to green light, the statement that exposure to blue light gives a high-contrast image and exposure to green light a low-contrast one, and that a magenta filter absorbs green and transmits blue while a yellow filter absorbs blue and transmits greenilfordphoto.com/wp/wp-content/uploads/2017/03/Contrast-control-for-Ilford-Multigrade.pdftier 1, primary2026-09-04
- 09PubChem compound summary: Pyrogallol (CID 1057)National Center for Biotechnology Information§ GHS classification — the aggregated ECHA notifications and the proportions behind each statementpubchem.ncbi.nlm.nih.gov/compound/1057tier 1, primary2026-09-04
- 10PubChem compound summary: Catechol (CID 289)National Center for Biotechnology Information§ GHS classification — the aggregated ECHA notifications and the proportions behind each statement; the California OEHHA statement citing IARCpubchem.ncbi.nlm.nih.gov/compound/289tier 1, primary2026-09-04
- 11Safety and Disposal Guidelines for the Use of Photographic ChemicalsEnvironmental Health and Safety, Florida Atlantic University§ Developers — the instruction to avoid pyrogallol and catechol and to substitute phenidonefau.edu/ehs/info/photo-chemicals-safety.pdftier 2, specialist2026-09-04
- 12EH40/2005 Workplace exposure limits, containing the list of workplace exposure limits for use with COSHHHealth and Safety Executive, 2005§ Introduction, paragraph 6 — that the absence of a substance from the list does not indicate that it is safehse.gov.uk/pubns/priced/eh40.pdftier 1, primary2026-09-04
Formulas, hazard statements, historical dates and process descriptions on this page were checked against the sources above on the date shown. Safety data changes: obtain the current safety data sheet for the product you actually buy before you open it.