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Level 4 · SpecialistCapstoneCapstone · page 9 of 10240 minSafety level B · Advanced home laboratoryCraftScienceArt££
240Minutes
10Chemicals
2Formulas
13Sources
BSafety level

Safety level B, advanced home laboratory. Needs additional controls, experience and precautions beyond the standard darkroom: stronger ventilation, splash protection, careful handling of concentrated reagents or of energies such as UV and low-voltage electronics.

Chemicals on this page10
Formulas on this page2

Capstone Stage 6: Permanence, Presentation and the Finished Portfolio

Requirement 11 asks you to evaluate the permanence of the portfolio. Not of a specimen, not of the process in general: of the objects you are actually submitting. That is the whole difficulty, and it is why this stage comes last.

A residual test on a print processed six weeks ago in a fixer whose capacity log you kept proves something about that print. The same test on a print processed yesterday in a bath you had stopped counting proves nothing about the first. So the tests here are run on the objects, or on companion sheets processed identically in the same run — and Stage 4’s instruction to carry an unexposed control sheet through every batch is what makes that possible now.

Then the set is reduced, sequenced, labelled and presented, and the rubric is filled in with a named piece of evidence behind every band claimed.

Level B, and it is the small volume of test chemistry rather than the mounting that sets the level. Silver nitrate is Danger with H272, H290, H314, H318, H360D, H400 and H410: an oxidiser that causes severe skin burns and serious eye damage, and stains skin black. It is handled with sealed chemical splash goggles, nitrile gloves and an apron; prepared in a small volume in a dedicated dropper bottle that is labelled and dated; kept away from the working surfaces; and collected as silver-bearing waste rather than rinsed away. Eyewash within reach before the bottle is opened.

A drop test is done on a sacrificial area over a tray, never over a finished print, and a tested sheet does not go back into the portfolio.

The rest of the page is Level A or lower, and saying which parts and why is part of the assessment. Trimming and mounting involve a sharp blade used towards a cutting mat; a tacking iron or press is a burn hazard and a fire hazard if left unattended; adhesives need ventilation. Nothing here needs a fume cupboard.

What is not a hazard here, and why. Handling the finished prints is chemically uneventful: a processed, washed, dried print carries no free reagent, and the substances that made it are locked in a hardened gelatin layer or have been carried out by the wash — which is precisely the claim the residual tests exist to check rather than assume. The board, the tissue and the box are inert materials at room temperature. The reason the same silver nitrate that is a dropper-bottle reagent here is a Level B substance is concentration and exposure route, not identity: a drop on a sacrificial margin is a very different proposition from a jar of solid being weighed. And the sulfide test’s reagent arrives as a dilution because Part XII settled that weighing the solid is Level C work done once, elsewhere — which the capstone does not permit at all.

Local regulation governs disposal of the silver-bearing test waste and this page gives no jurisdiction-specific instruction; read the disposal caveat.

Three tests, and one rule about what they are run on.

The rule. Test the actual work, on a sacrificial margin, or a companion sheet processed identically in the same run — the unexposed control sheet Stage 4 carried through every batch. A test on a different print from a different session is evidence about that session and nothing else.

Residual thiosulfate, by the SOP and under the Part XII criterion: process an unexposed white sheet of the same paper with the batch, cut a strip after the final wash, immerse it about three minutes in 1 per cent silver nitrate, rinse, and compare it wet, in subdued light, against the untreated part of the same sheet. No colour difference means the hypo has been removed; a yellow-brown tint means it is present.

Residual silver, by ILFORD’s sulfide test: a drop of the 1+9 dilution on a white area, blotted after a few seconds, read against a reference spot placed on a print known to be well fixed and thoroughly washed. Anything beyond a barely visible cream tint means the print is not properly fixed. The print must be well washed first; the test is not effective on a print straight from the fixer, and a reading taken there is no reading rather than a weak one.

The wash record for each work, which is not a test but is evidence: the sequence used, the batch it was in, the fixer’s rotation state and its running sheet count on the day.

A capstone portfolio contains objects made of different things, and their threats are not the same. Work this out per class rather than in general, because the storage plan follows from it and one portfolio may need incompatible storage.

The object What threatens it What follows
Untoned silver gelatin print Residual thiosulfate from the inside; oxidative attack from the air, giving image fade, silver mirroring and microspots The wash record and the enclosure. Mirroring starts at the edges, where the atmosphere reaches first, and IPI’s framing guide prints the unintended control experiment: a print mirrored under a poor mat, with the oval the window left uncovered still clear
Toned silver gelatin print The same threats, altered rather than removed. Conversion to silver sulfide or silver selenide is partial, so part of the image is still metallic silver The permanence statement says what was converted and what was not measured
Iron-blue print, or an iron-blue toned silver print Alkali. Prussian blue is destroyed by it, and the alkaline reserve that protects the paper attacks the image Unbuffered board, interleaving, enclosure and adhesive. This is the incompatibility that splits the portfolio
Iron-silver print (Van Dyke, kallitype) Residual iron from incomplete clearing; and humidity, which mobilises what is left The clearing record is part of the object’s evidence
Albumen print Yellowing of the binder, and a humidity sensitivity the binder’s own chemistry sets Stable humidity matters more here than an enclosure upgrade
Any of them Light. 30 to 100 lux on display, ultraviolet below 75 microwatts per lumen, and permanent display is not recommended The display advice on the label, not just in the statement

Choosing mounting and enclosure materials on evidence

Section titled “Choosing mounting and enclosure materials on evidence”

Four decisions, each made against a printed claim rather than a word on a packet.

The qualifying test is the Photographic Activity Test, ISO 18916. It puts the material in prolonged contact with two detectors: one screening for oxidation and reduction reactions that cause image fade, silver mirroring and red or gold spots, and one for chromophores that yellow the support. ISO 18902 then adds what the PAT does not cover: a pH between 7.0 and 9.5, an alkali reserve of at least 2 per cent calcium carbonate, a lignin content low enough to give a Kappa number of 7 or below, and a colorant-bleed test.

Passing is not a guarantee, and IPI say so twice. A material passing only the pH requirements or only the PAT is not necessarily photo-safe. And “photo-safe” refers only to the chemical reactivity of a material — it says nothing about abrasion, creases or tears. Meanwhile “acid-free”, “archival”, “museum-quality” and “conservation board” are, in IPI’s own words, not standardised or legal terms but simply marketing terms. The claim that means something is the printed sentence naming the standard.

Buffered or unbuffered is a decision per object, and one class of print inverts the usual answer. The Library of Congress recommend buffered paper at pH 7 to 9.5 for silver prints, platinum prints, chromogenic prints and acetate and nitrate films — and unbuffered paper at pH 6 to 7 for cyanotypes. So a portfolio containing an iron-blue print needs both kinds of board, and the two prints do not share an enclosure. Where a silver-gelatin print has been iron-blue toned, the course’s own reading — stated as the course’s, because no source it holds addresses that specific object — is to treat it as a Prussian blue object for every material it touches.

The attachment stays reversible. IPI’s position is that heat mounting, spray adhesive and pressure-sensitive tape are not recommended for preservation framing because they are not easily removable, and that it is best to choose a method that can be undone. That is the course’s default, and it settles the dry-mounting question for this specification: two hinges of Japanese tissue with a starch paste, or corners of an inert plastic or good paper. The argument is not that dry mounting damages a print; it is that a board which turns out to have been the wrong one can be replaced only if the print comes off it — and you are mounting objects whose enclosure requirements you have just discovered are not all the same.

A dry-mounted print may satisfy the specification’s “finished work” criterion if you argue the choice and record it. What it may not do is be presented as the conservation-preferred option, because the source this course holds says the opposite.

Glazing, where a work is framed: ISO 18902 recommends glazing that blocks at least 97 per cent of ultraviolet energy.

What stands between an oxidant and your image, in the order it is met

  1. The room30 to 50 per cent RH for a mixed collection without cycling more than 5 per cent a day, 30 to 40 per cent for photographs alone; 18 °C for extended-term storage with daily swings under ±2 °Clargest effect
  2. The enclosurePAT-passing, ISO 18902-compliant, buffered or unbuffered according to the object. A material that fails becomes a source rather than a barriercan be a source
  3. The bindergelatin, albumen, a resin coating — or, for a cyanotype, no binder at all, the pigment sitting in the paper fibresfixed when made
  4. The image materialmetallic silver, silver sulfide, silver selenide, Prussian blue, reduced silver on iron. Toning acts here, and partiallytoning acts here
  5. What you left in itresidual thiosulfate and residual silver, which need no arrival at all because they are already insidewashing and fixing act here
IPI's own ordering of effect: enclosures cannot overcome deficiencies in the storage climate, and improving the climate is more effective overall. Most people buy the boxes first.

Write down what your storage conditions actually are, not what an ideal would be. A cupboard in a heated interior room at whatever humidity your house runs at is a legitimate answer and a far better record than a set of figures copied from a leaflet. State the room, the enclosure, the orientation (flat or upright), whether the humidity cycles, and what you know about the air — a gas boiler, a laser printer, a newly painted wall, a workshop next door.

And state the display intention, because that is where the light figures bite: 30 to 100 lux, UV below 75 microwatts per lumen, and permanent display not recommended at all. A portfolio that will be shown occasionally and stored the rest of the time is in a different regime from one that will hang.

One line about the incompatibility. If your portfolio contains an iron-blue print, say in the storage plan that it is enclosed separately in unbuffered materials, and why. That sentence is the clearest evidence in the whole documentation set that the permanence work was done per object rather than in general.

One paragraph per class of object, to Part XX’s four-part template, and the four parts must not blur into one another.

The four parts, strongest first, and what each may contain

  1. What was doneMaterials, processing sequence, fixer and its rotation, wash route, toner with its dilution, time and temperature. Fact, and the part a stranger could repeat.
  2. What published procedure it followsNamed by publisher and document, with the document's date. Never by the word "archival".
  3. What was tested, and against what criterionThe residual tests, the criterion used, the result, and the date. Measurement — and the only sentence in the statement anyone can check.
  4. What is inferenceThat the toning protects. That the print will last. Anything about years. Clearly labelled as inference, or struck out.
The order encodes the rule: a reader must be able to tell which sentences they could check and which they are being asked to take on trust.

And every sentence carries its class. The capstone’s requirement 11 is a rule about sentences: a claim with no measurement behind it is written as an inference and never as a fact.

The second and harder subtraction. Stage 4 removed the print that did not belong; this one decides what the body of work is.

The constraint. At least one contact print, one enlarged silver print, one toned print and one alternative-process print must survive the cut, and they must be at least four separate works. Everything else is judgement.

The method. Lay the whole set out under the recorded judging station, at the recorded distance, and take three passes:

  1. Remove anything that fails a finishing test. Not dry, not flat, not spotted, not repeatable from its map. These are decisions about objects rather than about pictures and they are made first, because they are the only ones with a fixed answer.
  2. Remove what repeats. Where two works say the same thing, keep the one that says it better and record that you did. A set of ten in which three are variations is a set of eight.
  3. Remove a good print that does not serve the body of work. This is the pass the rubric’s coherence criterion rewards at its top band, and it is the one people skip. Name the print in the documentation and say why it went.

And check the arithmetic afterwards, because the constraint is easy to break in pass three: it is entirely possible to remove the only contact print because it is the weakest picture. If that happens, the answer is to reprint rather than to reinstate a print you have decided against.

Sequencing is the argument made visible. Part VII’s portfolio review already taught the method — an opening that teaches the viewer how to read the set, a scale contrast so the eye is not asked to do the same work twice, a pair hung adjacent so a difference is observed rather than explained, the quietest picture where attention dips, the strongest non-closing picture near the end, and a closing picture chosen for what it says rather than for how hard it was to make. Lay it out physically and walk past it twice before fixing it: an order that reads well on a table often does not read well as a line.

Two things a capstone adds to that method. Surface and image colour affect adjacency: a toned print beside an untoned one reads as a colour statement whether or not you meant one, and a matte sheet beside a glossy one reads as a material statement. And the alternative-process print is the hardest to place, because it is the object most obviously made of something else.

The presentation format was decided in the project plan and this is where it is executed: a mounted set, a portfolio box, or a bound sequence. Do not change it now — the prints were trimmed for it.

The labels carry the metadata the course has been recording all along, and this is the moment it pays off. One label per work:

Field Where it comes from
Title, or “untitled” with a number The portfolio statement’s vocabulary
Date of the exposure, and date of the print The exposure log and the printing map
Process Named precisely: “gelatin silver print”, “selenium-toned gelatin silver print”, “cyanotype”
Material Paper make, product, surface and weight; and the box code in the record if not on the label
Image size and sheet size Measured, not nominal
Negative reference The run and frame identifier from the exposure log
Process record reference The printing map version, and the session record
Where relevant, the treated-print record Toning session or coating record reference

That last pair is what distinguishes a capstone label from a gallery label. Anybody can print a title and a date. A label that lets a reader find the negative, the map and the session that made this object is the documentation set doing its job from the front of the print rather than the back.

Plain language, and short. What the work is about; what was made rather than bought; what the pictures are for.

The course’s style rules apply and they are worth stating as prohibitions because that is how they fail:

  • No marketing language. “Timeless”, “evocative”, “a celebration of” — none of these says anything, and they read as filling a space where an argument should be.
  • No journey. How you came to make the work is not what the work is about, and a statement that spends its first paragraph on the maker has spent it on the wrong subject.
  • No imagined reader. “The viewer is invited to consider” is a sentence with nobody in it.
  • No unsupported claims about the process. “Made with archival methods” belongs in the permanence statement, in its checkable form, or nowhere.

What replaces them: say what the pictures are of, what you were trying to find out or show, what you made yourself and why that mattered to the pictures, and what the set argues that the individual prints do not. Four sentences of that are worth two pages of the other thing.

Then read it against the paragraph you wrote at planning time, before any technical decision. The two will differ, and the difference is the most interesting thing in the documentation set: it is the record of what the project turned out to be about. Keep both, dated, and say in one sentence what changed.

Four criteria, four bands, and a named piece of evidence behind every band claimed — an artefact and a page, not a feeling. A band claimed with no named evidence scores as the band below it.

Work it as a table:

Criterion Band claimed The evidence, named
Accuracy of the chemistry and the numbers e.g. “Curve sheets 3–8; uncertainty statement p.11; the disagreement with the maker’s time discussed p.12”
Craft of the objects e.g. “Works 1–7; the remake comparison p.19; finishing record p.20”
Coherence of the body of work e.g. “Sequence sheet p.22; the removed print and the reason, p.23”
Honesty of the documentation e.g. “Declared substitutions p.4; the not-tested rows p.16; the statement of what is unknown p.24”

Then the four failure conditions, checked deliberately rather than assumed:

  • An unrecorded number. Read your own report with a pencil and mark every figure. Can each be traced to a notebook entry, a log line or a reading file?
  • A formula altered without saying so. Check the formula record against the source.
  • A permanence claim presented as measured when it was inferred. Read the statement sentence by sentence and label each one.
  • A work that cannot be reprinted from its own map. Demonstrated by trying, which you did in Stage 4.

And finish with the shortfalls. An honest list of what falls short and why, written by you, is worth more than a rubric with four fours in it — and under the honesty criterion it is what the top band actually requires. A capstone that names its own weakest point is a capstone whose other claims can be believed.

Every figure with a source is the planner’s own dated UK price. The run costed is one testing and presentation session for a six-work portfolio.

Consumed This session Sourced price Cost this session
Unexposed control sheets, already carried through the print batches 2 sheets of 8 × 10 RC £33.50 for 25 to £96.18 for 100 £1.92 to £2.68
Silver nitrate, for the residual-thiosulfate reagent 1 g, as 100 mL of 1 per cent £59.95 for 25 g to £112.90 for 10 g £2.40 to £11.29
Sodium sulfide stock, for the residual-silver test a few drops of the 1+9 dilution The price file could not price it. It is a gap the file names, and this test is one of the three uses it names the gap for
Conservation mount board, buffered 6 sheets The price file could not price it. It heads the conservation and presentation gap the file names, buffered and unbuffered separately
Conservation mount board, unbuffered 1 or 2 sheets, for an iron-blue work The price file could not price it
Japanese tissue and starch paste, or corners one set The price file could not price it
A portfolio box or presentation folder 1 The price file could not price it
Print and negative sleeving passing the Photographic Activity Test the set’s total Named in the price file’s own gap list as unpriced
Blade, cutting mat and straightedge consumed: blades only Named in the price file’s own gap list as unpriced

The priced rows come to about £4.32 to £13.97, and that figure is close to meaningless as a guide: seven of the nine consumables have no sourced price at all, and they are all of the presentation and enclosure materials. This is the stage where the price file is least useful and the planner’s cost band is the only honest guidance, and it is worth saying plainly that the half of the project on which requirement 11 depends is the half the course’s shopping data could not reach. Equipment used and not consumed — the cutting mat, the straightedge, the press if you use one — is in the prose above and deliberately not in this table.

No darkroom is needed for this stage at all. The tests are done in ordinary subdued room light on a bench, the mounting in daylight.

Unable to handle silver nitrate. The residual-thiosulfate test is unavailable and there is no substitute the course can offer: the alternative permanganate reagent in the historical literature needs a blank against oxidisable organic matter in the water supply that this course has not verified, and instrumental methods need a laboratory. Record the row as not testable, with the reason stated as a property of your circumstances, and write the permanence statement’s third part as an explicit absence: “Residual thiosulfate was not tested. The wash record for each work is given at p.N, and the statement below rests on the procedure followed rather than on a test of these objects.” That is a real loss of evidence and the specification says so — the accuracy criterion caps at band 3 — and it is still a defensible document.

Unable to obtain conservation materials. Every one of them is unpriced in this course’s shopping data, and in some places they are genuinely hard to buy. The route is to state what you used and what its packet claims, exactly as you would for a compliant material: “mounted on board whose packet makes no standards claim; the print is hinged with corners so that the board can be replaced”. That sentence is worth more than an unsupported claim to have used conservation board, and the reversible attachment is what makes the shortfall recoverable later.

No space to store the portfolio well. Say so. The storage plan asks for your actual conditions rather than an ideal, and “a closed box on an interior shelf in a heated room, humidity not measured” is a record a future reader can act on. IPI’s own ordering — that improving the climate does more than improving the enclosure — makes that sentence the most consequential one in the plan, which is exactly why it must be true.

The tests are run on the objects you are submitting or on companion sheets from the same run, they are comparisons rather than quantities, and they answer two different questions: the thiosulfate test is about the wash, the sulfide test is about the fixing. A negative result is bounded by your eye and the record says so.

The threats are worked out per object, because a portfolio containing an iron-blue print contains two incompatible storage requirements — buffered board for the silver prints, unbuffered for the Prussian blue — and finding that out is the point of doing it per object. The qualifying test for a material is the Photographic Activity Test with ISO 18902’s additional requirements, passing is not a guarantee, and the words on most packets are marketing terms. The attachment stays reversible, which is the course’s default and IPI’s recommendation, and it is what lets a board you chose wrongly be changed.

The permanence statement keeps its four parts separate and classifies every sentence, including at least one that says what you do not know. The set is reduced in three passes, sequenced as an argument, labelled so that a reader can find the negative and the map. The portfolio statement says what the work is about without a word of marketing. And the rubric is filled in with named evidence and an honest list of shortfalls, which is what its top band actually asks for.

Check your understanding

Question 1. You ran a residual-thiosulfate test in June on a print from batch 2 and it showed no colour difference. Your portfolio contains four prints from batch 2 and three from batch 5, made in September. What may you claim?
Show the answer and why

Answer: That the batch 2 prints met the course criterion on the day, and nothing about batch 5 — which needs its own companion sheet tested, because a fixer's state and a wash's effectiveness are properties of a run

The requirement is to evaluate the permanence of the objects you are submitting, and a run is the unit the evidence attaches to: a fixer three months older, a different sheet count against capacity and a different day's wash are three reasons batch 5 could differ. That is exactly why Stage 4 asks for an unexposed control sheet carried through every batch. The last option overstates the limit — a negative result is real evidence, just weaker than a positive one and bounded by the eye, the light and the control, which is what the record has to say.

Question 2. Your portfolio contains five gelatin silver prints and one cyanotype. What does the conservation evidence require of the mounting and enclosure materials?
Show the answer and why

Answer: Buffered board for the silver prints and unbuffered for the cyanotype, kept in separate enclosures — because the Library of Congress recommend buffered paper for silver prints and unbuffered at pH 6 to 7 for cyanotypes, Prussian blue being destroyed by alkali

This is the clearest case in the whole course of two works in one portfolio needing incompatible storage, and it is a genuine chemical conflict rather than a preference: the alkaline reserve that protects the paper attacks the pigment, and it is the image you cannot replace. Passing the PAT does not resolve it, because the PAT screens a material for chemical reactivity against its detectors and says nothing about whether an alkaline reserve suits the particular image material beside it. The practical consequence is two kinds of board and two enclosures, and a line in the storage plan saying why.

Question 3. Which of these sentences may appear in a capstone permanence statement as written?
Show the answer and why

Answer: "Toned in [product] at 1+20 for four minutes, the dilution and time the maker gives where the primary reason is protection of the image. The makers recommend toning as protection against oxidising gases; the degree of conversion achieved here was not measured, and no claim is made about how long this print will last."

Only the second keeps the four parts apart: what was done, at a stated dilution and time; the published procedure it follows, attributed to the maker; and the boundary of the claim, stated rather than implied. The first states an outcome where the evidence supports a mechanism at best. The third uses two terms IPI identify as marketing rather than standardised. And the fourth is the failure condition in its purest form — no source in this course's corpus attaches a figure in years to a print on the strength of its processing or toning, and the one standard written to measure conversion effectiveness explicitly prescribes no criterion a print can meet.

Question 4. IPI state that "enclosures cannot overcome deficiencies in the storage climate" and that improving the climate is more effective overall. What does that mean for the order of a capstone's permanence work?
Show the answer and why

Answer: Fix the wash and the fixing first because nothing later undoes them; then get the prints into a stable interior room; then buy better enclosures; then consider toning

The ordering follows the layers an attack passes through and the cost of each intervention. What the darkroom left inside the print needs no oxidant to arrive at all, and no enclosure or climate can remove it later — so it comes first and it is free. The room is the layer with the largest effect on every reaction above it, and moving a box from a loft to a heated interior room costs nothing. Enclosures matter and can become a source if they fail, but they act after the climate. Toning acts on the image material and is genuinely useful, and it is last on the list because it is the intervention with the most cost, the most hazard and the least measurable benefit for your particular print.

Sources for this page

13 cited · checked 2026-09-06

  1. 01Chemicals and Formulae, 3rd edition (one of a series of Kodak photographic handbooks)Kodak Limited, 1949§ TEST FOR HYPO — process with the batch an unexposed white sheet of photographic paper of the same weight and size as the majority of prints in the batch, cut off a strip after the final wash and immerse it in a 1 per cent silver nitrate solution for about three minutes, rinse it and compare it while wet, in subdued light, with the wet untreated portion; no colour difference means the hypo has been completely removed and a yellow-brown tint indicates its presence; and the caution that silver nitrate solution stains the skin blackarchive.org/details/KodakChemicalsAndFormulaetier 1, primary2026-09-05
  2. 02ILFORD RAPID FIXER, technical informationHARMAN technology Limited (ILFORD Photo), 2010§ Silver concentration — below 2 g/L when fixing FB papers where a high level of image permanence is required, approximately 40 prints of 20.3 by 25.4 cm per litre, and below 0.5 g/L for prints needing maximum stability for long-term storage, approximately 10 such prints; the sodium sulphide testing solution, 2 g in 125 ml diluted 1+9, read against a reference spot on a print known to be well fixed and thoroughly washed; and the note that silver estimator papers are usually not sensitive enough to test the very low silver levels suitable for optimum permanence, so that for important prints the paper itself is testedilfordphoto.com/amfile/file/download/file/1833/product/711tier 1, primary2026-09-05
  3. 03KODAK Processing Chemicals and Formulas for Black-and-White Photography, publication J-1, seventh edition 1973, updated 1977Eastman Kodak Company, Professional and Finishing Markets Division, 1977§ Printed page 41, TEST FOR HYPO and KODAK Hypo Test Solution HT-2 — the formula reading water 750 millilitres, KODAK 28% Acetic Acid 125.0 millilitres, KODAK Silver Nitrate Crystals 7.5 grams and water to make 1.0 litre; Testing Prints, the drop on the face of an unexposed piece of the same paper or on the extra margin of one of the prints, two minutes, rinsed, and compared with the tints shown in the KODAK Hypo Estimator; and TESTS FOR SILVER and KODAK Residual Silver Test Solution ST-1, the formula reading water 125 millilitres and Sodium Sulfide (Anhydrous) 2 grams, To Use diluted 1 part of stock with 9 parts of water, with the reading that any yellowing of the test spot other than a barely visible cream tint indicates the presence of silver. Read from the page images of the scan on 6 September 2026125px.com/docs/techpubs/kodak/j1-1977.pdftier 1, primary2026-09-06
  4. 04A Consumer Guide to Framing PhotographsImage Permanence Institute§ How to Select the Right Mat Board, Window Mats, and Backing Paper — that one of the best indicators of quality is that the board meets ISO 18902, that in addition to passing the Photographic Activity Test the standard requires all paper and paperboard materials to have a pH between 7.0 and 9.5, to be buffered with at least 2 per cent calcium carbonate and to be lignin-free, and that none of those requirements on its own implies sufficient preservation quality; How to Select the Right Mounting Method, that heat mounting, spray-adhesive mounting and pressure-sensitive tapes are not recommended for preservation framing because they are not easily removable and that it is best to select a method that can be undone; and the account of oxidation reactions from poor framing materials in which faded silver migrates to the surface and is converted back into metallic silver, forming a mirror-like sheenrit.edu/ipi/sites/rit.edu.ipi/files/documents/framing_guide.pdftier 1, primary2026-09-06
  5. 05Photo Storage, Display, & Labeling Materials: A Guide to ISO 18902 'Photo-Safe' TestingImage Permanence Institute§ The account of ISO 18916, the Photographic Activity Test, and of the additional requirements of ISO 18902 — the alkali reserve of at least 2 per cent calcium carbonate, the lignin limit expressed as a Kappa number of 7 or below, and the colorant-bleed test; the statement that a material passing only the pH requirements or only the PAT is not necessarily photo-safe; and the statement that photo-safe refers only to the chemical reactivity of a material and says nothing about abrasion, creases or tearsrit.edu/ipi/sites/rit.edu.ipi/files/documents/photo_safe_english.pdftier 1, primary2026-09-06
  6. 06Care, Handling, and Storage of PhotographsPreservation Directorate, Library of Congress§ Storage enclosures, which recommends paper made to ISO specifications buffered to a pH of 7 to 9.5, states that buffered paper may be used for acetate and nitrate films, platinum prints, silver prints, chromogenic prints and prints mounted on acidic boards, and that unbuffered paper tending to have a pH of 6 to 7 is recommended for cyanotypes and architectural drawings; Environment, for the 30 to 50 per cent relative humidity set point for a mixed collection without cycling more than 5 per cent a day, 30 to 40 per cent where only photographs are stored, and the 18 degrees C extended-term storage temperature taken from ISO 18920 with daily fluctuations greater than plus or minus 2 degrees C avoided; Light, for the 30 to 100 lux exhibit range, ultraviolet not exceeding 75 microwatts per lumen and the statement that permanent display is not recommended; and the account of oxidant gases, acidic and sulfiding gases and environmental fumesloc.gov/preservation/care/photolea.htmltier 1, primary2026-09-06
  7. 07ISO 18915:2000, Imaging materials - Methods for the evaluation of the effectiveness of chemical conversion of silver images against oxidation, first edition, 2000-12-14ISO/TC 42, Photography, 2000§ Published scope, clause 1.1, which states that the standard describes methods for evaluating the effectiveness of chemical conversion treatments intended to increase the resistance of wet-processed silver images to oxidation, that it does not recommend general or specific treatments, and that treatment temperature, times and replenishment rates are outside its scope. Read as the catalogue scope onlyiso.org/standard/31940.htmltier 1, primary2026-09-06
  8. 08Silver Gelatin, Photographic Materials Conservation CatalogAmerican Institute for Conservation, Photographic Materials Group§ The condition and deterioration account for silver gelatin prints, cited for the description of silver mirroring as a bluish metallic sheen beginning at the edges and visible under reflected light, and for the warning that mirrored areas are extremely susceptible to abrasion so that rubbing may move or remove image materialconservation-wiki.com/wiki/Silver_Gelatintier 1, primary2026-09-06
  9. 09The Atlas of Analytical Signatures of Photographic Processes: CyanotypeDusan C. Stulik and Art Kaplan, 2013§ The identification and material description of the cyanotype process, cited for the image-forming species and for the behaviour of Prussian blue as a pigment held in the paper fibresweb.archive.org/web/20140211090055id_/https://www.getty.edu/conservation/publications_resources/pdf_publications/pdf/atlas_cyanotype.pdftier 1, primary2026-09-06
  10. 10The Atlas of Analytical Signatures of Photographic Processes: Silver GelatinDusan C. Stulik and Art Kaplan, 2013§ Selenium Toning, which states that properly done archival selenium toning did not cause any major colour changes and that the high sensitivity of the XRF instrument allows detection of selenium even in photographs toned very briefly; and the sulfur-toning passage, which states that even when sulfur is clearly visible in the XRF spectrum the main source of the signal is not the Ag2S of the toned image but the sulfur of the BaSO4 of the baryta layer, which makes differentiating the source extremely difficultgetty.edu/conservation/publications_resources/pdf_publications/atlas.htmltier 1, primary2026-09-06
  11. 11IPI Media Storage Quick Reference, 2nd editionImage Permanence Institute§ The storage recommendations for photographic prints and negatives and the glossary definition of silver mirroring as oxidation of black-and-white images in which the image silver migrates to the surface, creating a mirror-like appearance; and the statement that enclosures cannot overcome deficiencies in the storage climate and that improving the climate is more effective overallrit.edu/ipi/sites/rit.edu.ipi/files/documents/msqr.pdftier 1, primary2026-09-06
  12. 12Toning Black-and-White Materials (KODAK Publication G-23, Technical Data / Reference)Eastman Kodak Company, 2006§ Page 1, that toning converts the black-and-white silver image to an inert compound and that all Kodak toners will protect the image whether or not they produce a colour shift125px.com/docs/techpubs/kodak/g23-Toners.pdftier 1, primary2026-09-06
  13. 13ILFORD MULTIGRADE FB WARMTONE: technical informationHARMAN technology Limited (ILFORD Photo), 2018§ The note beneath the optimum permanence sequences, that for optimum permanence with other toners that give a protective effect — sulphide, polysulphide and some metal replacement toners such as gold and platinum — the optimum permanence sequence is used first and the print toned afterwards, while other metal replacement toners such as blue (iron) and red (copper) may not give extra protection and the image might fade, and dye toners do not give extra protectionilfordphoto.com/amfile/file/download/file/1881/product/741tier 1, primary2026-09-06

Formulas, hazard statements, historical dates and process descriptions on this page were checked against the sources above on the date shown. Safety data changes: obtain the current safety data sheet for the product you actually buy before you open it.